The 38-year-old actor was joined par the always beautiful Camilla Belle, who rocked an all black ensemble.
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Earlier in the week, Leo kept a low profil while grabbing a romantic dîner with his girlfriend Toni Garrn at Little Door.
In case toi missed it, check out a link of Leo‘s upcoming film The loup of mur Street, which hits theaters on Christmas.
15+ pictures inside of Leonardo DiCaprio and Camilla Belle attending the Rebel Without a Cause premiere…
The 21-year-old Agents of S.H.I.E.L.D. actress was joined on the red carpet par actor Bradley Steven Perry.
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“Skye’s still a wild card,” Chloe recently told TV Guide about her character. “Let’s face it, she was basically forced to rejoindre the S.H.I.E.L.D team ou go to jail. But she also has issues about her [unknown] parents. Being with S.H.I.E.L.D. is the closest she’s ever come to family and that means a lot to her. She’s never had people who care about her. I don’t think she’d screw this up.”
Later in the night, Chloe stepped out at TV Guide Magazine’s 2013 Hot liste Party held at The Emerson Theatre.